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推荐专家

张兴宏

来源:本站原创2015年12月14日

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  • 工作单位

    浙江大学

  • 研究方向

    聚碳酸酯多元醇,高性能/无卤阻燃环氧树脂,3D打印线材和光固,油墨技术及产品

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  • 手机号码

    13588846711

  • E-mail

    xhzhang@zju.edu.cn

  • 姓名

    张兴宏

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    77975232

  • 性别

    微信

    d_xhzhang

专家简介


  浙江大学高分子科学与工程学系副教授,博士,博士生导师。近年来作为项目负责人主持国家自然科学基金项目4项;浙江省杰出青年基金项目1项;中国博士后自然科学基金一等资助项目1项;浙江省自然科学基金项目1项;浙江省科技厅社会公益技术项目1项;承担香港建滔化工集团、德国巴斯夫委托的国内外研究课题4项。在Chemical Science, Macromolecules, Polymer Chemistry, Macromolecular Rapid Communications, Journal of polymer science Part A: Polymer Chemistry, Polymer 等国内外期刊发表 SCI论文50余篇,授权中国发明专利20项,授权美国专利1项。

  主持/参与科研项目

  主持的国家级项目:

  1、一釜合成多嵌段CO2基共聚物及其结构与性能、国家自然科学基金面上项目、2015/01-2018/12。

  2、氧硫化碳-环氧化物可控催化共聚及机理研究、国家自然科学基金面上项目、2013/01-2016/12。

  3、基于CO2/环氧化物可控共聚技术合成可降解的聚合物分子刷、国家自然科学基金面上项目、2011/01-2013/12。

  专利、论文及著作

  代表性专利:

  1. Metal cyanide complex catalyst, preparation method and uses thereof,美国发明专利,授权,US13394267,2014.10, 1/5。

  2. 一种链结构规整的聚单硫代碳酸酯的制备方法 ,发明专利,授权,201310202810.0, 2015.05,1/4。

  3. 一种用于碳酸二甲酯合成的催化剂的制备方法及应用,发明专利,授权,201210148342.9,2014.04,1/4。

  4. 一种纳米结构环氧树脂固化物的制备方法和用途,发明专利,授权,201010225029.1,2012.03,1/3。

  5. 一种链结构规整的脂肪族聚碳酸酯的合成方法,发明专利,授权, 201310035031.6,2015.02,1/3。

  6. 一种双组分双金属催化剂的合成方法及应用,发明专利,授权, 201110428195.6,2015.04,1/4。

  7. 含聚酯链节和聚碳酸酯链节的三元共聚物及其合成方法,发明专利,授权,200910098650.3,2011.05,1/3。

  8. 主链和侧链均为碳-氧杂链结构的聚合物分子刷、合成方法,发明专利,授权, 201110249714.2,2013.08,1/5。

  9. 金属氰化物配位催化剂催化制备脂肪族聚碳酸酯的方法,发明专利,授权, 201010253928.2,2012.05,1/5。

  10. 一种金属氰化物配位催化剂及其制备方法和应用,发明专利,授权,201010253936.7,2012.05,1/5。

  论文:

  2015

  (1) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Well-defined high refractive index poly(monothiocarbonate) with tunable Abbe's numbers and glass-transition temperatures via terpolymerization. Polymer Chemistry 2015, 6, 4978-4983.

  (2) Li, Y.; Hong, J.-L.; Wei, R.-J.; Zhang, Y.-Y.; Tong, Z.-Z.; Zhang, X.-H.*; Du, B.-Y.; Xu, J.-T.; Fan, Z.-Q. Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone. Chemical Science 2015, 6, 1530-1536.

  (3) Zhang, Y.-Y.; Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Efficient solvent-free alternating copolymerization of CO2 with 1, 2-epoxydodecane and terpolymerization with styrene oxide via heterogeneous catalysis. Journal of Polymer Science Part A: Polymer Chemistry 2015, 53, 737-744.

  (4) Zhang, Y.-Y.; Li, Y.; Zhou, X.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Synthesis of an Amphiphilic Brush Copolymer by a Highly Efficient “Grafting onto” Approach via CO2 Chemistry. Macromolecular Rapid Communications 2015, 36, 852-857.

  (5) Zhang, X.-H.*; Wei, R.-J.; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q. Carbon Dioxide/Epoxide Copolymerization via a Nanosized Zinc–Cobalt(III) Double Metal Cyanide Complex: Substituent Effects of Epoxides on Polycarbonate Selectivity, Regioselectivity and Glass Transition Temperatures. Macromolecules 2015, 48, 536-544.

  (6) Min, Y.-Q.; Huang, S.-Y.; Wang, Y.-X.; Zhang, Z.-J.; Du, B.-Y.; Zhang, X.-H.*; Fan, Z.-Q. Sonochemical Transformation of Epoxy–Amine Thermoset into Soluble and Reusable Polymers. Macromolecules 2015, 48, 316-322.

  (7) Luo, M.; Zhang, X.-H.*; Darensbourg, D. J. An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane. Macromolecules 2015, 48, 5526-5532.

  (8) Luo, M.; Zhang, X.-H.*; Darensbourg, D. J. An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide. Macromolecules 2015, 48, 6057-6062.

  (9) Luo, M.; Zhang, X. H.*; Darensbourg, D. J. Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether. Polymer Chemistry 2015, 6, 6955-6958.

  (10)Luo, M.; Zhang, X. H.*; Darensbourg, D. J. Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides. Catalysis Science & Technology 2015. Advance Article. DOI: 10.1039/C5CY00977D

  2014

  (1) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Alternating copolymerization of carbonyl sulfide and Cyclohexene Oxide catalyzed by zinc–cobalt double metal cyanide complex. Polymer 2014, 55, 3688-3695.

  (2) Wei, R.-J.; Zhang, X.-H.*; Zhang, Y.-Y.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Functional poly (carbonate-co-ether) synthesis from glycidyl methacrylate/CO2 copolymerization catalyzed by Zn–Co (III) double metal cyanide complex catalyst. RSC Advances 2014, 4, 3188-3194.

  (3) Wei, R.-J.; Zhang, Y.-Y.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q. Regio-selective synthesis of polyepichlorohydrin diol using Zn–Co (III) double metal cyanide complex. RSC Advances 2014, 4, 21765-21771.

  (4) Zhang, Y.-Y.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of fully alternating polycarbonate with low T g from carbon dioxide and bio-based fatty acid. RSC Advances 2014, 4, 36183-36188.

  (5) Zhang, X.-H.*; Min, Y.-Q.; Hua, Z.-J. Epoxy-Based Electronic Materials Containing Nitrogen Heterocyclic Ring: Flame Retardancy. Progress in chemistry 2014, 26, 1021-1031.

  (6) Hong, J.-L.; Zhang, X.-H.*; Wei, R.-J.; Wang, Q.; Fan, Z.- Q.; Qi, G.-R. Inhibitory effect of hydrogen bonding on thermal decomposition of the nanocrystalline cellulose/poly (propylene carbonate) nanocomposite. Journal of Applied Polymer Science 2014, 131.

  (7) Zhou, X.-J.; Zhou, Y.-Y.; Nie, J.-J.; Xu, J.-T.; Zhang, X.-H.; Du, B.-Y.* Thermosensitive Ionic Microgels

  via Surfactant-Free Emulsion Copolymerization and in Situ Quaternization Cross-Linking. ACS Applied Materials & Interfaces 2014, 6, 4498-4513.

  (8) Chen, T.-Q.; Lu, Y.-P.; Chen, T.-Y.; Zhang, X.-H.; Du, B.-Y.* Adsorption of PNIPAm x-PEO 20-PPO 70-PEO 20-PNIPAm x pentablock terpolymer on gold surfaces: effects of concentration, temperature, block length, and surface properties. Physical Chemistry Chemical Physics 2014, 16, 5536-5544.

  2013

  (1) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Sun, X.-K.; Fan, Z.-Q.; Qi, G.-R. Highly Regioselective and Alternating Copolymerization of Racemic Styrene Oxide and Carbon Dioxide via Heterogeneous Double Metal Cyanide Complex Catalyst. Macromolecules 2013, 46, 3693-3697.

  (2) Luo, M.; Zhang, X.-H.*; Du, B.-Y.; Wang, Q.; Fan, Z.-Q. Regioselective and Alternating Copolymerization of Carbonyl Sulfide with Racemic Propylene Oxide. Macromolecules 2013, 46, 5899-5904.

  (3) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Selective production of poly (carbonate–co–ether) over cyclic carbonate for epichlorohydrin and CO2 copolymerization via heterogeneous catalysis of Zn–Co (III) double metal cyanide complex. Polymer 2013, 54, 6357-6362.

  (4) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Synthesis of bis (cyclic carbonate) and propylene carbonate via a one-pot coupling reaction of CO2, bisepoxide and propylene oxide. RSC Advances 2013, 3, 17307-17313.

  (5) Wei, R.-J.; Zhang, X.-H.*; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Highly Active and Selective Binary Catalyst System for the Coupling Reaction of CO2 and Hydrous Epoxides. Journal of Molecular Catalysis A: Chemical 2013, 379, 38-45.

  (6) Lu, Y.-P.; Chen, T.-Q.; Mei, A.-X.; Chen, T.-Y.; Ding, Y.-W.; Zhang, X.-H.; Xu, J.-T.; Fan, Z.-Q.; Du, B.-Y.* Solution behaviors and microstructures of PNIPAm-P123-PNIPAm pentablock terpolymers in dilute and concentrated aqueous solutions. Physical Chemistry Chemical Physics 2013, 15, 8276-8286.

  (7) Chen, T.-Y.; Du, B.-Y.*; Zhang, X.-H.; Fan, Z.-Q. Fabrication of Polymer Nanocapsules with Controllable Oligo (Ethylene Glycol) Densities, Permeation Properties and Robustly Crosslinked Walls. ACS Applied Materials & Interfaces 2013, 5, 3748-3756.

  2012

  (1) Sun, X.-K.; Zhang, X.-H.*; Wei, R.-J.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. Mechanistic insight into initiation and chain transfer reaction of CO2/cyclohexene oxide copolymerization catalyzed by zinc-cobalt double metal cyanide complex catalysts. Journal of Polymer Science Part A: Polymer Chemistry 2012, 50, 2924-2934.

  (2) Sun, X.-K.; Chen, S.; Zhang, X.-H.*; Qi, G.-R. Double Metal Cyanide Complex Catalyst and Its Catalysis for Epoxides-Involved Polymerization. Progress in Chemistry 2012, 24, 1776-1784.

  (3) Lu, Y.-P.; Zhang, X.-H.; Fan, Z.-Q.; Du, B.-Y.* Adsorption of PNIPAm 110-PEO 100-PPO 65-PEO 100-PNIPAm 110 pentablock terpolymer on hydrophobic gold. Polymer 2012, 53, 3791-3801.

  2011

  (1) Zhang, J.-F.; Ren, W.-M.; Sun, X.-K.; Meng, Y.; Du, B.-Y.; Zhang, X.-H.* Fully Degradable and Well-Defined Brush Copolymers from Combination of Living CO2/Epoxide Copolymerization, Thiol–Ene Click Reaction and ROP of ε-caprolactone. Macromolecules 2011, 44, 9882-9886.

  (2) Zhang, X.-H.*; Wei, R.-J.; Sun, X.-K.; Zhang, J.-F.; Du, B.-Y.; Fan, Z.-Q.; Qi, G.-R. Selective copolymerization of carbon dioxide with propylene oxide catalyzed by a nanolamellar double metal cyanide complex catalyst at low polymerization temperatures. Polymer 2011, 52, 5494-5502.

  (3) Meng, Y.; Zhang, X.-H.*; Du, B.-Y.; Zhou, B.-X.; Zhou, X.; Qi, G.-R. Thermosets with core–shell nanodomain by incorporation of core crosslinked star polymer into epoxy resin. Polymer 2011, 52, 391-399.

  2010

  (1) Sun, X.-K.; Zhang, X.-H.*; Chen, S.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. One-pot terpolymerization of CO2, cyclohexene oxide and maleic anhydride using a highly active heterogeneous double metal cyanide complex catalyst. Polymer 2010, 51, 5719-5725.

  (2) Mei, A.-X.; Guo, X.-L.; Ding, Y.; Zhang, X.-H.; Xu, J.-T.; Fan, Z.-Q.; Du, B.-Y.* PNIPAm-PEO-PPO-PEO-PNIPAm pentablock terpolymer: synthesis and chain behavior in aqueous solution. Macromolecules 2010, 43, 7312-7320.

  (3) Huang, Y.-J.; Zhang, X.-H.*; Hua, Z.-J.; Qi, G.-R. Calcium chloride doped zinc-cobalt metal-cyanide complex: Unexpected highly activity towards ring-opening polymerization of propylene oxide. Chinese Chemical Letters 2010, 21, 897-901.

  (4) Huang, Y.-J.; Zhang, X.-H.*; Hua, Z.-J.; Chen, S.-L.; Qi, G.-R. Ring‐Opening Polymerization of Propylene Oxide Catalyzed by a Calcium‐Chloride‐Modified Zinc‐Cobalt Double Metal‐Cyanide Complex. Macromolecular Chemistry and Physics 2010, 211, 1229-1237.

  2009

  (1) Zhou, B.-X.; Huang, Y.-J.; Zhang, X.-H.*; Fu, Z.-S.; Qi, G.-R. Thermal properties of an epoxy cresol‐formaldehyde novolac/diaminodiphenyl sulfone system modified by bismaleimide containing tetramethylbiphenyl and aromatic ether structures. Polymer Engineering & Science 2009, 49, 1525-1532.

  (2) Zhang, X.-H.*; Zhou, B.-X.; Sun, X.-K.; Qi, G.-R. Cure kinetics and thermal properties of tetramethylbiphenyl epoxy resin/phthalazinone‐containing diamine/hexa (phenoxy) cyclotriphophazene system. Journal of Applied Polymer Science 2009, 114, 1397-1404.

  (3) Huang, Z.-Z.; Zhang, X.-H.*; Qi, G.-R. Novel halogen-free flame retardant thermoset from a hybrid hexakis (methoxymethyl) melamine/phosphorus-containing epoxy resin cured with phenol formaldehyde novolac. Express Polym. Lett 2009, 3, 788-796.

  (4) Du, B.-Y.*; Cao, Z.; Li, Z.-B.; Mei, A.-X.; Zhang, X.-H.*; Nie, J.-J.; Xu, J.-T.; Fan, Z.-Q. One-Pot preparation of hollow silica spheres by using thermosensitive poly (N-isopropylacrylamide) as a reversible template. Langmuir 2009, 25, 12367-12373.

  2008

  (1) Zhang, X.-H.*; Liu, F.; Sun, X.-K.; Chen, S.; Du, B.-Y.; Qi, G.-R.; Wan, K.-M. Atom-exchange coordination polymerization of carbon disulfide and propylene oxide by a highly effective double-metal cyanide complex. Macromolecules 2008, 41, 1587-1590.

  (2) Zhang, X.-H.*; Zhou, B.-X.; Sun, X.-K.; Qi, G.-R. Preparation and properties of epoxy/phenol formaldehyde novolac/hexakis (methoxymethyl) melamine hybrid resins from in situ polymerization. Journal of Applied Polymer Science 2008, 110, 4084-4092.

  (3) Sun, X.-K.; Zhang, X.-H.*; Liu, F.; Chen, S.; Du, B.-Y.; Wang, Q.; Fan, Z.-Q.; Qi, G.-R. Alternating copolymerization of carbon dioxide and cyclohexene oxide catalyzed by silicon dioxide/Zn-Co(III) double metal cyanide complex hybrid catalysts with a nanolamellar structure. Journal of Polymer Science Part A:Polymer Chemistry 2008, 46, 3128-3139.

  2007

  (1) Zhang, X.-H.; Hua, Z.-J.; Chen, S.; Liu, F.; Sun, X.-K.; Qi, G.-R.* Role of zinc chloride and complexing agents in highly active double metal cyanide catalysts for ring-opening polymerization of propylene oxide. Applied Catalysis A: General 2007, 325, 91-98.

  (2) Zhang, X.-H.; Liu, F.; Chen, S.; Qi, G.-R.* Novel flame retardant thermosets from nitrogen‐containing and phosphorus‐containing epoxy resins cured with dicyandiamide. Journal of Applied Polymer Science 2007, 106, 2391-2397.

  (3) Zhang, X.-H.; Chen, S.; Wu, X.-M.; Sun, X.-K.; Liu, F.; Qi, G.-R.* Highly active double metal cyanide complexes: Effect of central metal and ligand on reaction of epoxide/CO2. Chinese Chemical Letters 2007, 18, 887-890.

  (4) Zhang, X.-H.*; Huang, L.-H.; Chen, S.; Qi, G.-R. Improvement of thermal properties and flame retardancy of epoxy-amine thermosets by introducing bisphenol containing azomethine moiety. eXPRESS Polymer Letters 2007, 1, 326-332.

  (5) Zhang, X.-H.; Chen, S.; Chen, T.; Sun, X.-K.; Liu, F.; Qi, G.-R.* Synthesis of a soluble azomethine‐containing bisphenol and the properties of its modified epoxy thermosets. Journal of Applied Polymer Science 2007, 106, 1632-1639.

  (6) Chen, S.; Zhang, X.-H.; Lin, F.; Qi, G.-R.* Preparation of double metal cyanide compleces from water-insoluble zinc compounds and their catalytic performance for copolymerization of epoxide and CO2. Reaction Kinetics and Catalysis Letters 2007, 91, 69-75.

  2006

  (1) Zhang, X.-H.; Chen, S.; Min, Y.-Q.; Qi, G.-R.* Synthesis of novel bisphenol containing phthalazinone and azomethine moieties and thermal properties of cured diamine/bisphenol/DGEBA polymers. Polymer 2006, 47, 1785-1795.

  (2) Zhang, X.-H.; Min, Y.-Q.; Zhao, H.; Wan, H.-M.; Qi, G.-R.* Novel nitrogen‐containing epoxy resin. II. Cure kinetics by differential scanning calorimetry. Journal of Applied Polymer Science 2006, 100, 3483-3489.

  著作:

  1, Yuan Meng, Xinghong Zhang*. Nanostructure Formation in Thermoset/Block Copolymer and Thermoset/Hyperbranched Polymer Blends (pages 161-194, Chapter 6 of book: Nanostructured Polymer Blends, edited by Sabu Thomas, Robert Shanks et al), Elsevier Inc, 2013-12, ISBN(ASIN): 1455731595, 条形码: 978-1-4557-3159-6, William Andrew publishing(出版社);丛书名: Micro & Nano Technologies

  2, Yuan Meng, Xinghong Zhang*. Nanostructured epoxy composites (Chapter 3 of book: Micro and Nanostructured Epoxy/Rubber Blends), Wiley-VCH Verlag GmbH, 2014-02. ISBN(ASIN) 3527333347,条形码:978-3-527-33334-9, Germany.

  提供技术

  聚碳酸酯多元醇合成技术及其产品;

  高性能/无卤阻燃环氧树脂;

  绿色增塑剂;

  3D打印线材和光固化油墨技术及产品。

  获得荣誉

  1、发表在Polymer上的论文《Selective copolymerization of carbon dioxide with propylene oxide catalyzed by a nanolamellar double metal cyanide complex catalyst at low polymerization temperatures》 (2011, 52(24), 5494-5502)获得2012年度冯新德最佳论文提名奖(ELSEVIER出版社)。

  2、 2014年 《粘接》杂志,《非异氰酸酯路线合成聚羟氨酯的研究》在“中国胶粘剂行业首届优秀科技论文有奖征文大赛”中,获得“杰出奖”论文的荣誉。

  3、

  2013年浙江大学求是青年学者;

  2012年浙江省自然科学学术奖三等奖,排名1;

  2012年校级教学成果奖,排名第五;

  浙江大学2014年度院级先进工作者.

  团体/社会/学术兼职

  1. 国家自然科学基金评审专家;浙江省自然科学基金通讯评议人

  2. 浙江省粘接技术协会常务理事(2014-2019);

  3.《粘接》杂志特约撰稿人(2015-2017)。

 



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