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用于结构胶粘剂方面的填料和添加剂

来源:林中祥胶粘剂技术信息网2011年02月06日

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Fillers and Extenders for Structural Adhesives

 


Fillers and extenders are used in structural adhesive formulations to improve properties and to lower cost. Properties that can be selectively improved include both the processing properties of the adhesive as well as its performance properties in a cured joint. However, the use of fillers can also impair certain properties. Typically, the formulator has to balance the expected improvements against possible property decline.

Fillers and extenders generally have different functions and are employed for different reasons. However, these functions may overlap, and then fillers and extenders can be thought of as serving the same purpose depending on the application.

This article reviews the reasons for using and the types of fillers and extenders that are commonly employed in structural adhesive formulations. Epoxy adhesives are the focus due to their popularity and general use in many industries. However, much of what is presented also extends to structural adhesives in general.

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用于结构胶粘剂方面的填料和添加剂 Definitions

Fillers are relatively non-adhesive substances added to the adhesive formulation to improve its working properties, strength, permanence, or other qualities. The advantages and disadvantages of filler addition in epoxy formulations are listed in Table 1. Common fillers used in epoxy formulations and the properties that they are used to modify are shown in Table 2. Some fillers may act as extenders. This is the case when their primary function is to reduce formulation cost.

Advantages
Disadvantages
Advantage or Disadvantage (Depending on Application)
  • Lower cost of product
  • Reduced shrinkage on curing
  • Decreased exothermic temperature on curing
  • Improved tensile-shear strength
  • Increased surface hardness
  • Improved abrasion resistance
  • Improved heat aging properties
  • Increased compressive strength
  • Increased electrical strength
  • Improved toughness if fibrous fillers are used
  • Increased weight
  • Increased water absorption (depending on filler)
  • Loss of transparency
  • Difficulty in machining hard fillers
  • Increased viscosity
  • Increased thermal and electrical conductivity
  • Reduced thermal expansion coefficient
Table 1: Advantages and Disadvantages of Fillers in Structural Adhesive Formulations

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Filler
Improvement in Adhesive

Aluminum

Machineability

Alumina

Abrasion resistance, electrical

Aluminum silicate

Extender

Aluminum trioxide

Flame retardant

Barium sulfate

Extender

Calcium carbonate

Extender

Calcium sulfate

Extender

Carbon black

Pigment, reinforcement

Copper

Machineability, electrical conductivity

Glass fiber

Reinforcement

Graphite

Lubricity

Iron

Abrasion resistance

Kaolin clay

Extender

Lead

Radiation shielding

Mica

Electrical resistance