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Green Chemistry

来源:林中祥胶粘剂技术信息网2011年02月24日

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                    Green Chemistry




"Green chemistry" is considered to be a relatively new term but actually it has been around for quite some time. It is the design of chemical products and processes that reduce or eliminate the use and generation of hazardous materials. All market sectors relying on chemistry are turning to the principles of "green chemistry" as a foundation for future development. The current state-of-the-art in green chemistry has been reached due to advances in research, implementation, and education over the past decade. However, the growth of green chemistry practices needs to increase at an accelerated pace if we are to meet the challenges of the future.

This article reviews the origins of green chemistry and describes the basic principles involved. The factors that are driving the growth of green chemistry in todays adhesives and sealants industry are identified. The responsibilities of the raw material supplier and the adhesive formulator relative to green chemistry are also discussed in this review.


Green Chemistry The Origins of Green Chemistry

The production of green chemicals, polymers, and even ready-to-use adhesive products from renewable sources is not new.

  • More than 100 years ago, well known U.S. botanist George Washington Carver made rubber from sweet potatoes and ink, dye, and insulating board from peanuts. Working to solve the challenge of crop surpluses, he developed some 300 industrial uses for an inexpensive, renewable raw material - the peanut.
  • Henry Ford developed a method of manufacturing plastic parts for automobiles from soybeans in the 1930s. However, World War II sidetracked the production of bioplastic cars.
  • Since anyone can remember on the island of St. Bartholomew in the French West Indies, school children have used the juice of berries as a pressure sensitive adhesive. Almost everyone on the island refers to the tree as a Glue Tree or Pied de Colle. Not only is the adhesive environmentally friendly but the adhesive comes in its own biodegradable container - possibly the ultimate "green" adhesive.

As a result of this work and others, the foundation for todays green materials was developed. Biopolymers and other raw materials derived from renewable sources are gaining popularity once again as new manufacturing techniques have developed through biotechnology or what has become known as "green chemistry".

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Green Chemistry Drivers Behind Green Chemistry

Over the years, the environmental drivers in the adhesives industry have been a blend of regulations, special interest group pressure, and corporate marketing. Several laws and non-government programs have evolved to have a profound impact on the chemical industry. This was the primary driver toward development and commercialization of a number of new adhesive systems over the last several decades.

Today, the primary driver of regulation is still there, but several others are making impact. Among these are geo-political tensions, economic climate concerns, and popular re-definition of the problem (e.g., "global warming", "sustainability") and other issues. This has generated environmental awareness within the adhesive community beyond reduction in VOC levels.


Green Chemistry Principles of Green Chemistry

The principles of George Washington Carvers breakthroughs are still being exploited - now we define it as "green chemistry". It is concerned with developing processes and products to reduce or eliminate hazardous substances. One of the goals of green chemistry is to prevent pollution at its source, as opposed to dealing with pollution after it has occurred. The set of principles summarized in Table 1 provide the framework for todays chemists and material engineers to design products and processes with minimal impact on the environment.

Principle Response
Prevent waste Design chemical synthesis to prevent waste, leaving nothing to treat or clean-up.
Design safer chemicals and productsDesign chemical products to be fully effective with little or no toxicity.
Design less hazardous chemical synthesisDesign synthesis to use and generate substances with little or no toxicity to humans and the environment.
Use renewable feedstockUse raw material and feedstock that are renewable rather than depleting.  Renewable feedstocks are often made from agricultural products or are the wastes of other processes.
Use catalysts, not stoichiometric reagentsMinimize waste by using catalytic reactions.  Catalysts are used in small amounts and can carry out a single reaction many times.  They are preferable to stoichiometric reagents, which are used in excess and work only once.
Avoid chemical derivativesAvoid using blocking or protecting groups, or any temporary modification, if possible.  Derivatives use additional reagents and generate wastes.
Maximize "atom" economyDesign syntheses so that the final product contains the maximum proportions of the starting materials.  There should be few, if any, wasted atoms.
Use safer solvents and reaction conditionsAvoid using solvents, separation agents, or other auxiliary chemicals.  If these chemicals are necessary, use innocuous chemicals.
Increase energy efficiencyRun chemical reactions at am
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